Organic Chemistry

Cer-katalysierte, oxidative C-C-Kupplungsreaktionen: Neue - download pdf or read online

By Irina Geibel

Irina Geibel zeigt eine leading edge Anwendungsmöglichkeit des preiswerten und ökologisch unbedenklichen Seltenerdmetallsalzes CeCl3 · 7 H2O bei der Knüpfung von C-C-Bindungen mit Luftsauerstoff als Oxidationsmittel auf. Ziel der Arbeit ist die Entwicklung einer neuen atomökonomischen, umwelt- und ressourcenschonenden Eintopfsynthese zur Darstellung von 1,4 Diketonen. In GC-kontrollierten Ansätzen werden für eine Beispielreaktion zahlreiche Reaktionsparameter variiert und dokumentiert. Unter Anwendung der optimierten Reaktionsbedingungen werden 1,4-Diketone hergestellt, die abschließend als Ausgangsverbindungen in Anellierungsreaktionen eingesetzt werden.  

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Cer-katalysierte, oxidative C-C-Kupplungsreaktionen: Neue Umpolungsreaktion zur Synthese von 1,4-Diketonen (BestMasters) (German Edition) by Irina Geibel


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